Hi @menapears
I checked your Family Plan account and I can confirm that both invitations have been sent out.
I did notice the email address starting with mbmena****@*****.com has no device associated with it and no listening history. If this is your husbands account it doesn't appear to have been used.
In the meantime, can you tell me a little more about the device he's using when listening, is this in-home, mobile or web?
If this is happening with an in-home device, can you tell me a bit more about the advertising you are hearing? Is it for a specific brand or artist? Are you hearing them while listening to podcasts?
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